Accordingly, two commercial copper extractants, Acorga M5774 and LIX 984N were used in extraction of copper from a sulfate–chloride solution containing seawater. The results showed a higher concentration of copper in the pregnant leach solution (PLS) as a result of using seawater; however, the concentration of Fe and the …
Various chelating ligands have been investigated for the cloud point extraction of several metal ions. However, limited studies on the use of the Schiff base ligands have been reported. In this work, cloud point extraction behavior of copper(II) with N,N′-bis(salicylaldehyde)Ethylenediimine Schiff base chelating ligand, (H2SALEN), was …
Copper can be extracted from non-sulfide ores by a different process involving three separate stages: Reaction of the ore (over quite a long time and on a huge scale) with a dilute acid such as dilute sulfuric …
Copper extraction from the chloride-sulfate solution4.1.1. Effects of pH. The effects of the pH and chloride concentration on the extraction of copper were investigated. The obtained results are shown in Fig. 11 for pH value and chloride concentration ranging from 1 to 2.75 and 0 to 40 g/L, respectively.
Abstract This research investigates the extraction behavior of copper and zinc from the sulfate leachate of a porcelain stone tailings sample with Chemorex CP-150 and D2EHPA in detail. The findings demonstrated that Chemorex had greater ability and selectivity in the extraction of copper, while D2EHPA was better in the extraction of …
DOI: 10.1016/J.SEPPUR.2013.10.045 Corpus ID: 94485206; Solvent extraction of copper, zinc, cadmium and nickel from sulfate solution in mixer settler unit (MSU) @article{Jha2014SolventEO, title={Solvent extraction of copper, zinc, cadmium and nickel from sulfate solution in mixer settler unit (MSU)}, author={Manish Kumar Jha and Divika …
Fig. 4 presents the copper extraction and the extent of sulphate formation in experiments T2-T4 and T6 where the mixing intensity was the same in all tests, i.e. 2.4 kW/m 3. Also, T7 is presented (with a high mixing intensity of 13 kW/m 3). It can be seen that copper extraction increased with increasing sulphate formation in these tests (Fig. …
The technique of low-temperature roasting with ammonium sulfate has been regarded as a promising and cleaner process for direct extraction of valuable metals from low-grade laterite ores (Li et al., 2017), exhibiting many excellent characteristics including high metal recovery, high reaction selectivity, low energy consumption and low cost.The …
Obtained experimental data were used to develop a method of copper(II) extraction from Zn-Cu sulfate solution composed of 40.9 g/L Zn(II) and 1.2 g/L Cu(II). A flowsheet was tested in laboratory-scale reactors and the conducted test confirmed the possibility to selective recover of Cu(II) over Zn(II), and the concentration of Cu(II). ...
The effect of chloride ions on the copper extraction equilibria, the rate of extraction, copper/iron selectivity, and chloride extraction was studied for organic phases containing pure ketoxime (LIX 84-IC) and pure nonylaldoxime (LIX 860N-IC). In these systems, the used aqueous phase contained total chloride concentrations from 0 to 110 g/l.
Copper Smelting means that the concentrated ore is heated strongly with silicon dioxide (silica), calcium carbonate (CaCO 3) and air in a furnace. The major steps in the extraction of copper are. Copper in …
The liquid-liquid extraction of copper(II) from sulphate and perchlorate media by salicylideneaniline (HSA) in chloroform is studied. The ionic strength effect of the aqueous phase shows that the extraction of copper(II) increases with decreasing concentration of sulphate. At initially 10–4 m in the aqueous phase, Cu(II) is extracted …
The anodes cast from processed blister copper are placed into an aqueous solution of 3-4% copper sulfate and 10-16% sulfuric acid. Cathodes are thin rolled sheets of highly …
The extraction of copper from sulfate leaching liquor was investigated using Acorga M5640 commercial extractant in kerosene diluent. The effects of important factors such as the extractant ...
In order to extract copper from the sulfate solution in continuous mode in mixer settler unit, basic studies have been made for the copper extraction at different pH, extraction isotherms, O/A ratio, etc. using 5% LIX 84 diluted in kerosene.
Copper extraction from leachates of malachite and chalcopyrite ore samples was performed in order to validate extraction results from the synthetic solutions. ... an aqueous solution was obtained by dissolving a known mass of glycine in deionised water to which copper sulphate was added to complex with the glycine at 1:3 ratio in a …
Then electrolytic refining of copper is carried out to remove the rest of the impurities present in the ore. The impure copper is made anode and strip of pure copper are made cathode. On passing the current as shown in the diagram, the pure copper from the anode dissolves into an electrolyte. An equivalent amount of copper is deposited on the ...
Copper can be extracted from non-sulphide ores by a different process involving three separate stages: Reaction of the ore (over quite a long time and on a huge scale) with a …
Various extractants have been applied in the copper extraction from sulfate medium (Sole and Hiskey, 1995; Devi, ... reported the copper extraction from chloride medium using N-alkyl-3-pyridinecarboxamides and N,N-di-alkyl-3-pyridinecarboxamides and determined the extracted species being CuCl 2 L 2, where L stands for the …
The copper sulphate solution obtained after leaching also contained cobalt and zinc as valuable metals. ... Rodriguez de San Miguel et al. (1997), the selectivity of LIX 984 for copper extraction lies in the pH range 0.5–2.5. Copper extraction from the pregnant liquor was carried out in three stages with 12% v/v LIX 984 diluted with …
Copper converter slag, provided by Ergani Copper Co. of Etibank and containing 2.56% copper and 0.22% cobalt, was roasted with ammonium sulfate. The effects of such parameters as temperature (200–600°C), duration of roasting (15–120 min), and amount of ammonium sulfate (0.5–2.5 times stoichiometric) have been studied.
Sulfide in the mineral is oxidised to sulfate without the generation of SO 2 or H 2 S. The best selective recovery of copper (99 at%) from chalcopyrite was obtained with a mixed …
1. Introduction. Ferric and/or cupric chloride leaching processes have been extensively studied to treat sulfide concentrates of copper, lead, and zinc (Dutrizac, 1992, Peters, 1977).Chloride leaching has the following advantages over sulfate systems: (1) supporting high metal solubility, (2) enhanced redox behavior, (3) increased rates of …
A simple solvent extraction method was developed to extract copper (II) from sulfate solution. The extraction of copper (II) with furfuryl thioalcohol was investigated. The effect of variables ...
The extraction mechanism was proposed based on the slope analysis, UV-Visible and FTIR spectra. 2 Experimental 2.1 Reagents Aqueous phase reagents: …
Nevertheless, despite the enhanced copper extraction to some extent, some disadvantages still exist. In acidic sulfate media, the kinetics of copper dissolution is generally slow (several months) ... Copper extraction from chalcopyrite in [EMIm]HSO 4-K 2 Cr 2 O 7 leaching system is closely related to the temperature, ...
There are two steps in the extraction of copper metal from chalcocite, a copper ore. In the first step, copper (I) sulfide and oxygen react to form copper (I) oxide and sulfer dioxide: 2Cu2S(s) + 3O2(g) → 2Cu2O(s) + 2SO2(g) In the second ste ... Copper sulfate is a hydrated crystal with the formula CuSO_4 cdot 5H_2O and a deep blue ...
Use this practical to produce copper from copper(II) carbonate, modelling the extraction of copper from malachite. Malachite is a copper ore consisting mainly of basic copper(II) carbonate, CuCO3.Cu(OH)2. In this experiment, students learn how to produce copper from copper(II) carbonate by heating it to produce copper(II) oxide, which is then ...
copper sulfate solution.29 The salt can then be further crystallized or recovered as metal, e.g., in electrowinning. Nowadays, copper extraction and recycling pro-cesses need to …
Under optimal conditions, the extraction of cobalt and copper reached 86.2 and 95.9 pct, respectively. Then, the phase transformation of main minerals during the activation roasting was studied. ... The peak at 768 °C was due to the partial decomposition of copper sulfate, which resulted in the intermediate products, CuO·CuSO 4 and …
The liquid-liquid extraction of copper(II) from sulphate and perchlorate media by salicylideneaniline (HSA) in chloroform is studied. The ionic strength effect of the aqueous phase shows that the ...